Bubbling fluidization has been widely applied in process industries, such as power generation from coal, renewable energy production, gasification and pyrolysis. In this study, we attempted to predict solid flow patterns, solid and gas mixing, bubble behaviour in a bubbling fluidized bed based on operational conditions and bed design.
Pore wetting is a principal control of the multiphase flows through porous media. However, the contact angle measurement on other than flat surfaces still remains a challenge. In order to indicate the wetting in a small pore, we developed a new pore contact angle measurement technique to directly measure the contact angles of fluids and gas/liquid/supercritical CO2 in micron-sized pores under ambient and reservoir conditions in this study, as well as the effect of chemical functional groups on pore contact angle.
Enhanced oil/gas recovery and CO2 storage are a displacement process at pore scale, in which oil and gas are displaced by water or CO2 in reservoir at pore scale, or water is displaced by CO2 in aquifers at pore scale. This displacement is controlled by pore structure, pore wettability, pore surface chemistry, fluid viscosity and interfacial interaction between pore fluids and pore surfaces. The displacement controls the pore connectivity, therefore oil/gas recovery and CO2 storage capacity. We investigate the displacement and the effect of various factors on the displacement at pore scale and core scale.
To address the need for effective vis response photocatalysts, we have synthesised WO3 and TiO2 nanowires to provide a fast transport channel for the photo-generated electrons which can retard the charge recombination. We are working on improving the visible activity of the catalysts through modifying the nanocomposites using metal (Ag, W, V, Fe, Ni) and non-metal (C, N, B, S) elements, and through the control over the microstructure or even over the crystal phase.
In optimizing the properties of functional materials it is essential to understand in detail how structure influences properties. Identification of the most important structural parameters is time-consuming and usually investigated by preparing many different chemical modifications of a material, determining their crystal structures, measuring their physical properties and then looking for structure-property correlations. It is also necessary to assume that the chemical modifications have no influence other than to distort the structure, which is often not the case.
Membrane processes are a promising alternative to the more classical post-combustion capture technologies due to the reduced maintenance of the process, the absence of dangerous solvents and their smaller footprint. This project aims at supporting the development of new mixed matrix membranes for post-combustion applications. Mixed matrix membranes (MMMs) are composite materials formed by embedding inorganic fillers into a polymeric matrix in order to overcome the upper bound and combine the characteristics of the two solid phases: mechanical properties, economical processing capabilities and permeability of the polymer and selectivity of the filler. Despite several studies on the concept, the interactions between the two phases and their effect on the transport properties are not well understood. Yet, this fundamental knowledge is crucial in order to design the reliable materials needed for real-world-applications.
The general objective of CleanCOALtech project is: to create and develop an educational and training system for promoting, developing and implementing clean coal technologies, through knowledge and best practices shared from advanced EU country – UK to South-East European region – Romania and Greece in order to provide high performance and innovation in the vocational education and training systems and to raise stakeholders level of knowledge and skills.
The research focuses on develop a microwave swing technique to selectively heat solid at molecular level for adsorbent regeneration, and then compare the results with temperature swing. The project is supported by EPSRC.
Carbon capture from power stations and industrial sources is an essential pillar in the effort of reducing greenhouse gas emissions in order to achieve the legally binding target set by the 2008 Climate Change Act of 80% reductions by 2050. The current state-of-the-art technologies for post-combustion capture (including retrofit options for existing plants) are based on amine scrubbers, but inherent energy requirements make this an expensive option and significant research is aimed at the development of next generation carbon capture processes that reduce the cost of capital equipment and the energy needed.